کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309185 | 975198 | 2010 | 5 صفحه PDF | دانلود رایگان |
New metallopolymers were generated efficiently on Pt and ITO (indium–tin oxide) glass slides by repeated scan oxidation of Ru and Fe complexes containing pyrrolostyryl bipyridine ligands. The UV–Vis spectrum and voltammogram of Ru-based polymer films showed blue-shifts of the MLCT absorption bands and increased oxidation potentials indicating conjugation cut in the π-extended system. In contrast, formation of polypyrrole occurred in Fe-based polymers due to oxidation of pyrrole groups by the initially oxidised metal centres. The coated ITO electrodes displayed promising wide absorption domains for use in light conversion devices.
New metallopolymers were generated efficiently on Pt and ITO glass slides by repeated scan oxidation of Ru and Fe complexes containing pyrrolostyryl bipyridine ligands. The coated ITO electrodes displayed promising wide absorption domains for use in light conversion devicesFigure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 7, 20 April 2010, Pages 1404–1408