کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310104 | 975231 | 2014 | 11 صفحه PDF | دانلود رایگان |
• Dendritic carbosilane N-alkyl-N′-mesityl NHC ligands were synthesized.
• A Grubbs I type dendritic olefin metathesis catalyst was developed.
• The activity of this catalyst relative to commercial catalysts was studied.
The synthesis and characterization of monomeric and dendritic Grubbs II and Hoveyda–Grubbs II-based complexes are reported. These complexes were synthesized via a route based on the connection of monomeric or dendritic N-alkyl-N′-mesitylimidazol-2-ylidene pre-ligands to Grubbs I or Hoveyda–Grubbs I complexes. The immobilization of a modified Grubbs II type catalyst on a G0 carbosilane dendrimer was successfully carried out. Together with monomeric Grubbs II and Hoveyda–Grubbs-analogs and several commercially available olefin metathesis catalysts, the soluble, homogeneous G0-dendritic Grubbs II complex was tested as catalyst in the ring closing metathesis of diethyl diallylmalonate. The immobilized complex proved to outperform its monomeric analog in this reaction at room temperature, whereas it was found to be slightly slower at reflux temperature.
The synthesis and characterization of monomeric and dendritic Grubbs II and Hoveyda-Grubbs II-based complexes are reported. Together with several commercially available olefin metathesis catalysts, these complexes were used in the ring closing metathesis of diethyl diallylmalonate.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 409, Part A, 1 January 2014, Pages 163–173