کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312505 | 1499204 | 2012 | 13 صفحه PDF | دانلود رایگان |
Zinc (II), cobalt (II) and copper (II) phthalocyanines substituted at the peripheral (complexes 5, 6 and 7) and non-peripheral (complexes 8, 9 and 10) positions with 7,8-(15-crown-5)-3-(4-oxyphenyl)coumarin groups have been prepared and characterized. The photophysical and photochemical properties of zinc (II) Pc complexes (5 and 8) were also described. The singlet oxygen quantum yields (0.54 for 5, 0.65 for 8) are indicating the potential of the complexes as photosensitizers in applications of PDT. The redox processes of the complexes were identified by voltammetry and in situ spectroelectrochemistry. Alpha and beta-substituted complexes displayed metal- and/or phthalocyanine ring-based redox processes. It was found that the kind of substitution affects the redox processes of the phthalocyanine complexes considerably, due to the difference in their aggregation behaviors.
Zinc (II), cobalt (II) and copper (II) phthalocyanines substituted at the peripheral and non-peripheral positions with 7,8-(15-crown-5)-3-(4-oxyphenyl)coumarin groups have been prepared and characterized. The photophysical and photochemical properties of zinc (II) Pc complexes were also described. The singlet oxygen quantum yields are indicating the potential of the zinc (II) Pc complexes as photosensitizers in applications of PDT. The redox processes of the complexes were identified by voltammetry and in situ spectroelectrochemistry.Figure optionsDownload as PowerPoint slideHighlights
► Synthesis and characterization of novel phthalocyanine complexes are reported.
► Crown ether bearing coumarin substituted Zn, Co and Co phthalocyanines are studied.
► Photophysical, photochemical and electrochemical properties are investigated in DMSO.
► The effect of the position of the substituents on these properties is also reported.
Journal: Inorganica Chimica Acta - Volume 383, 30 March 2012, Pages 287–299