کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1313084 | 975527 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and X-ray crystal structure determination of a useful PdII starting compound, enPd(NO3)2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and X-ray crystal structure determination of a useful PdII starting compound, enPd(NO3)2 Synthesis and X-ray crystal structure determination of a useful PdII starting compound, enPd(NO3)2](/preview/png/1313084.png)
چکیده انگلیسی
Dinitrato(ethylenediamine)palladium(II) has been crystallized from aqueous solution following treatment of enPdCl2 with AgNO3. The en ligand is chelating and the two nitrate ligands bind monofunctionally. When brought in water, the nitrates are immediately replaced by water ligands, thus providing a convenient source of highly reactive [enPd(H2O)2]2+. 1H NMR spectra of the title compound in dimethylformamide and acetonitrile indicate proton exchange between NH2 groups of en ligands.
Dinitrato(ethylenediamine)palladium(II) is a convenient source of enPdII for reactions carried out in water. Its preparation, X-ray crystal structure determination, and 1H NMR spectra are reported.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 5, 20 March 2006, Pages 1485–1488
Journal: Inorganica Chimica Acta - Volume 359, Issue 5, 20 March 2006, Pages 1485–1488
نویسندگان
Marta Morell Cerdà, Burkhard Costisella, Bernhard Lippert,