کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322533 | 977213 | 2011 | 7 صفحه PDF | دانلود رایگان |

The synthesis and structure of palladium(II) complexes bearing uridato/pyridyl ligands as an anionic N-donor coordination sites are reported. The complexes have been shown to be highly active catalysts for the Heck reaction of aryl bromides (TON 4.0×104–9.1×104) and moderate activity for the activation of aryl chlorides under phosphine-free conditions.
The synthesis and structure of palladium(II) complexes bearing uridato/pyridyl ligands as an anionic N-donor coordination sites are reported. The complexes have been shown to be highly active catalysts for the Heck reaction of deactivated aryl bromides (TON 4.0×104–9.1×104) and moderate activity with the aryl chlorides under phosphine-free conditions.Figure optionsDownload as PowerPoint slideResearch highlights
► Palladium(II) complexes bearing new uridato/pyridyl ligands as an anionic N-coordinate sites.
► Heck reaction under phosphine-free conditions.
► High TON in the coupling of deactivated aryl bromides.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 3, 1 February 2011, Pages 795–801