کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322643 | 1499898 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A phenyldithiocarbazate-functionalized polyvinyl chloride resin-supported Pd(II) complex as an effective catalyst for solvent- and copper-free Sonogashira reactions under aerobic conditions A phenyldithiocarbazate-functionalized polyvinyl chloride resin-supported Pd(II) complex as an effective catalyst for solvent- and copper-free Sonogashira reactions under aerobic conditions](/preview/png/1322643.png)
• The catalyst was prepared by immobilization of palladium complex on PVC and was fully characterized.
• The catalyst exhibited efficient catalytic activity in Sonogashira reactions under aerobic condition.
• The catalyst can be reused several times without a noticeable change in activity.
The PVC-supported phenyldithiocarbazate palladium complex was prepared and characterized. The catalyst exhibits excellent catalytic activity and stability for the Sonogashira coupling reaction under ambient conditions. Various terminal alkynes were coupled with a number of aryl halides in the presence of 1.0 mol% of the catalyst to afford the corresponding products in high yields. Furthermore, the heterogeneous catalyst can be readily recovered by simple filtration and reused for several times without a significant loss in its activity.
PVC-supported phenyldithiocarbazate palladium complex was found to be an efficient catalyst in the palladium-catalyzed copper-free Sonogashira reactions of aryl halides under aerobic conditions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 740, 15 September 2013, Pages 78–82