کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1322961 | 1499915 | 2013 | 8 صفحه PDF | دانلود رایگان |
N,N′,N″,O-Tetrafunctional Pd(II) complexes prepared from the easily available amino acids are shown to be highly efficient catalysts for the Heck reaction of deactivated aryl bromides and iodides with high turnover numbers up to ca.104 and moderate activity for the activation of aryl chlorides under phosphine-free conditions.
N,N′,N″,O-Tetrafunctional Pd(II) complexes prepared from the easily available amino acids are shown to be highly efficient catalysts for the Heck reaction of deactivated aryl bromides and iodides with high turnover numbers up to ca.104 and moderate activity for the activation of aryl chlorides under phosphine-free conditions.Figure optionsDownload as PowerPoint slideHighlights
► N,N′,N″,O-Tetrafunctional Pd(II) complexes prepared from amino acids.
► Highly efficient catalysts for Heck reaction of deactivated aryl bromides and iodides.
► High turnover numbers up to ca.104.
Journal: Journal of Organometallic Chemistry - Volume 723, 1 January 2013, Pages 129–136