کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325154 | 977372 | 2009 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Opening “Jaws”: Functionalisation of the hexaphosphapentaprismane cage, P6C4tBu4, affording X2P6C4tBu4 (X = Me, I), crystal and molecular structures of X2P6C4tBu4 (X = Me, I) and [cis-PtCl2Me2P6C4tBu4] Opening “Jaws”: Functionalisation of the hexaphosphapentaprismane cage, P6C4tBu4, affording X2P6C4tBu4 (X = Me, I), crystal and molecular structures of X2P6C4tBu4 (X = Me, I) and [cis-PtCl2Me2P6C4tBu4]](/preview/png/1325154.png)
The hexaphosphapentaprismane cage, P6C4tBu4 (“Jaws”), can be readily opened by reaction with iodine at room temperature to afford the di-iodo derivative I2P6C4tBu4 which can be converted to the dimethyl derivative Me2P6C4tBu4 by treatment with LiMe. Me2P6C4tBu4 behaves as a bidentate ligand towards PtCl2. The molecular structures of all the new compounds have been determined by 31P and/or 195Pt NMR spectroscopy and single crystal X-ray diffraction studies.
The hexaphosphapentaprismane cage, P6C4tBu4 (“Jaws”), can be readily opened by reaction with iodine at room temperature to afford the di-iodo derivative I2P6C4tBu4 which can be converted to the dimethyl derivative Me2P6C4tBu4 by treatment with LiMe. Me2P6C4tBu4 behaves as a bidentate ligand towards PtCl2. The molecular structures of all the new compounds have been determined by 31P and/or 195Pt NMR spectroscopy and single crystal X-ray diffraction studies.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 26, 15 December 2009, Pages 4223–4229