کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326194 | 977420 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A new catalytic route to synthesis of silylgermylethynes A new catalytic route to synthesis of silylgermylethynes](/preview/png/1326194.png)
Silylgermylethynes known to be potential organometallic reagents and precursors of optoelectronic materials can be efficiently synthesized via a recently reported catalytic method called silylative coupling of alkynes with vinylsilicon compounds. The reaction of triethylethynylgermane with vinyltrisubstituted silanes catalyzed by [RuHCl(CO)(PR3)n] (where R = iPr, Cy, Ph; n = 2–3) under optimal conditions selectively yields respective silylgermylethynes. Silylation of ethynylgermane with divinylsilicon derivatives such as siloxanes, silazanes, bis(silyl)benzene and bis(silyl)ethane gives monoethynylgermyl substituted vinyldisilicon products with high yields and selectivity, however, accompanied by traces of dialkynylgermyl derivatives. All catalytic results as well as those of stoichiometric study on the insertion of ethynylgermane into Ru–Si bond have permitted proposing mechanistic schemes of the reaction examined.
Vinylsubstituted silicon compounds (divinyldisilicon derivatives) react selectively with triethylethynylgermane in the presence of complexes containing [Ru]–H and [Ru]–Si bonds with formation of silylgermylethynes (monoethynylgermyl substituted vinyldisilicon products). The reaction opens a new catalytic route for preparation of a class of silylgermylethynes and vinylsilylgermylalkynyl derivatives of both, acetylene and vinyl functionalities, potent organosilicon reagents and precursors for organic synthesis.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 2, 15 January 2008, Pages 235–240