کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326866 | 977448 | 2008 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterization of tris{2-(N,N-bis(diphenylphosphino) aminoethyl} amine derivatives: Application of a palladium(II) complex as a pre-catalyst in the Heck and Suzuki cross-coupling reactions Synthesis and characterization of tris{2-(N,N-bis(diphenylphosphino) aminoethyl} amine derivatives: Application of a palladium(II) complex as a pre-catalyst in the Heck and Suzuki cross-coupling reactions](/preview/png/1326866.png)
The polydendate bis(phosphino)amine, tris{2-(N,N-bis(diphenylphosphino)aminoethyl}amine 1 has been prepared in a single step from the reaction of tris(2-aminoethyl)amine with six equivalents of PPh2Cl in the presence of NEt3 in THF. Oxidation of 1 with aqueous H2O2, elemental sulfur or grey selenium gave the corresponding oxide, sulfide or selenide derivatives. [{(P(E)Ph2)2NCH2CH2}3N] (E: 2a O, 2b S, 2c Se), respectively. Reaction of [{(PPh2)2NCH2CH2}3N] with 3 equiv. of PdCl2(cod) or PtCl2(cod) gave the corresponding chelate complexes, [Pd3Cl61] or [Pt3Cl61]. The new compounds were fully characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of the Pd(II) complex was tested in the Suzuki coupling and Heck reactions. The Pd(II) complex catalyzed the Suzuki coupling and Heck reaction affording biphenyls and stilbenes, respectively, in high yields.
Metal complexes {Pd (II) and Pt (II)} and oxidation products of tris{2-(N,N-bis(diphenylphosphino)aminoethyl}amine, [{(PPh2)2NCH2CH2}3N] 1 have been prepared and characterized. The catalytic behaviour of the Pd(II) complex was investigated in the Suzuki coupling and Heck reactions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 26, 15 December 2008, Pages 3810–3814