Ba5Ti12Sb19+x, a polar intermetallic compound with a stuffed γ-brass structure

The polar intermetallic compound Ba5Ti12Sb19+x (x⩽0.2) has been synthesized by reaction of the elements. Single-crystal X-ray diffraction analysis revealed that it adopts a new structure type (Ba5Ti12Sb19.102(6), space group P43¯m, Z=2, a=12.4223(11) Å, V=1916.9(3) Å3). The set of Ba and Sb sites corresponds to the structure of Cu9Al4, a γ-brass type with a primitive cell. A complex three-dimensional framework of Ti atoms, in the form of linked planar Ti9 clusters, is stuffed within the γ-brass-type Ba–Sb substructure. Notwithstanding its relationship to the γ-brass structure, the compound does not appear to conform to the Hume–Rothery electron concentration rules. Band structure calculations on an idealized Ba5Ti12Sb19 model suggest that the availability of bonding states above the Fermi level is responsible for the partial occupation, but only to a limited degree, of an additional Sb site within the structure. Magnetic measurements indicated Pauli paramagnetic behaviour.

A γ-brass substructure built up of Ba–Sb clusters is stuffed with planar Ti9 clusters.Figure optionsDownload as PowerPoint slide