کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1329604 | 1500095 | 2015 | 7 صفحه PDF | دانلود رایگان |
• The first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 is reported.
• Hydrothermal conditions (240 °C, 3d) were used for the synthesis of K3Na[B6O9(OH)3]NO3.
• Borate Sechserrings are interconnected through hydrogen-bonding.
The first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 was synthesized under hydrothermal conditions from Na2B4O7·10H2O and K2B4O7·4H2O using KNO3 as a nitrate source. The compound crystallizes in the space group Pnnm (no. 58) with the lattice parameters a=1320.8(3), b=910.7(2), and c=1232.5(3) pm (Z=4). Isolated Sechserrings formed by BO4 and BO3 groups are linked through hydrogen bridges to form a three-dimensional network.
The first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 was synthesized under hydrothermal conditions from Na2B4O7·10H2O and K2B4O7·4H2O using KNO3 as a nitrate source.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 221, January 2015, Pages 66–72