Microwave assisted hydrothermal synthesis of Ag/AgCl/WO3 photocatalyst and its photocatalytic activity under simulated solar light

Simulated solar light responsive Ag/AgCl/WO3 composite photocatalyst was synthesized by microwave assisted hydrothermal process. The synthesized powders were characterized by X-Ray Diffraction (XRD) spectroscopy, X-Ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Diffuse Reflectance Spectroscopy (UV–Vis DRS), and BET surface area analyzer to investigate the crystal structure, morphology, chemical composition, optical properties and surface area of the composite photocatalyst. This photocatalyst exhibited higher photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation. Dye degradation efficiency of composite photocatalyst was found to be increased significantly as compared to that of the commercial WO3 nanopowder. Increase in photocatalytic activity of the photocatalyst was explained on the basis of surface plasmon resonance (SPR) effect caused by the silver nanoparticles present in the composite photocatalyst.

Graphical AbstractFigure optionsDownload as PowerPoint slideHighlights
► Successful synthesis of Ag/AgCl/WO3 nanocomposite.
► Photocatalytic experiment was performed under simulated solar light.
► Nanocomposite photocatalyst was very active as compared to WO3 commercial powder.
► SPR effect due to Ag nanoparticles enhanced the photocatalytic activity.