Functionalization of multi-walled carbon nanotubes by epoxide ring-opening polymerization

In this study, covalent functionalization of carbon nanotubes (CNTs) was accomplished by surface-initiated epoxide ring-opening polymerization. FT-IR spectra showed that polyether and epoxide group covalently attached to the sidewalls of CNTs. TGA results indicated that the polyether was successfully grown from the CNT surface, with the final products having a polymer weight percentage of ca. 14–74 wt%. The O/C ratio of CNTs increased significantly from 5.1% to 29.8% after surface functionalization of CNTs. SEM and TEM images of functionalized CNTs exhibited that the tubes were enwrapped by polymer chains with thickness of several nanometers, forming core–shell structures with CNTs at the center.

Functionalized CNTs were enwrapped by polymer chains with thickness of several nanometers, forming core–shell structures with CNTs at the center.Figure optionsDownload as PowerPoint slideHighlights
► CNTs were functionalized by epoxide ring-opening polymerization.
► Polyether and epoxide group covalently attached to the sidewalls of CNTs.
► Functionalized CNTs have a polymer weight percentage of ca. 14–74 wt%.
► Functionalized CNTs were enwrapped by polymer chains with thickness of several nanometers.