Synthesis of YAG nanopowder by the co-precipitation method: Influence of pH and study of the reaction mechanisms

YAG nanopowders with an average grain size of 30 nm have been successfully synthesized by the co-precipitation method using nitrates with precipitant of ammonium hydrogen carbonate. The influence of precipitation conditions such as pH, aging time and calcination temperature on the formation of secondary phases has been studied. The accurate control of pH value at every stage of precipitation process is crucial to avoid the presence of YAM (Yttrium Aluminium Monoclinic, Y4Al2O9) and yttrium oxide (Y2O3) after calcination. The reaction mechanisms have been investigated using different techniques such as infrared spectroscopy, x-ray diffraction and thermal analyses. The YAG phase is formed around 1050 °C passing through an intermediate phase called YAP (Yttrium Aluminium Perovskite, YAlO3). Local chemical heterogeneities are responsible for the deviation of the Y:Al ratio and the formation of YAP during heat treatment.

Synthesis of YAG nanopowder by the co-precipitation method: Influence of pH and study of the reaction mechanisms, Marlot et al. Figure optionsDownload as PowerPoint slideHighlights
► Synthesis of pure YAG nanoparticles by the co-precipitation method.
► Influence of pH value on the formation of secondary phases all along the process.
► Study of the importance of pH using titration method.
► Chemical evolution of the precursor during calcinations.
► Proposition for reaction mechanisms.