Synthesis of high efficient Ca2SiO4:Eu2+ green emitting phosphor by a liquid phase precursor method

Green emitting Eu2+-doped Ca2SiO4 phosphors were synthesized by three different methods (a conventional solid state reaction (SSR) method, a novel liquid phase precursor approach using SiO2 sol (LPP-SiO2(sol)) and water-soluble silicon compound (LPP-WSS)). The obtained phosphors exhibited a broad excitation spectrum ranging from 225 to 450 nm and a strong green emission peak at 502 nm due to the 4f65d1→4f7(8S7/2) transition of Eu2+. The highest luminescent intensity was obtained for the samples fired at 1100 °C. The dependence of luminescence properties on Eu2+ concentration for the phosphors synthesized using LPP-WSS method was also examined from 0.1 to 5.0 mol% and the maximum emission intensity was observed at 3.0 mol% Eu2+. A detailed analysis using various characterizations revealed that phosphors produced by the LPP-WSS process exhibited more homogenous phase distribution and higher luminescence intensity than those from the other two processes, which suggested the potential application of Ca2SiO4:Eu2+ in white light-emitting diodes and fluorescence lamps.

The synthesis of Eu2+ doped Ca2SiO4 green emitting phosphors were carried out using LPP-SiO2(sol), LPP-WSS and SSR methods. The adequate reaction of starting materials base on solution mixing and cellulose impregnating during LPP-WSS procedure resulted in single crystalline structure as well as fine morphology, and finally determined a superior luminescent intensity.Figure optionsDownload as PowerPoint slideHighlights
► Ca2SiO4:Eu2+ phosphor was synthesized by three methods (SSR, LPP-SiO2 and LPP-WSS).
► Effect of different processes on the property of phosphor was studied.
► Phosphor produced by LPP-WSS showed better homogenous phase and fluorescent property.
► LPP-WSS approach was identified as the best method among these three approaches.