Solvothermal synthesis of Zn2GeO4:Mn2+ nanophosphor in water/diethylene glycol system

The influence of aging of the suspension containing the amorphous precusors on structural, compositional and photoluminescent properties is studied to understand the mechanism on the formation of Zn2GeO4:Mn2+ nanoparticles during the solvothermal reaction in the water/diethylene glycol mixed solvent. Aging at 200 °C for 20 min forms the crystalline Zn2GeO4 nanorods and then they grow up to ∼ 50 nm in mean length after aging for 240 min. Their interplanar spacing of (410) increases with increasing the aging time. The photoluminescence intensity corresponding to the d–d transition of Mn2+ increases with increasing the aging time up to 120 min, and then decreases after aging for 240 min. The photoluminescence lifetime decreases with increasing the aging time, indicating the locally concentrated Mn2+ ions. These results reveal that Mn2+ ions gradually replace Zn2+ ions near surface through repeating dissolusion and precipitation processes during prolonged aging after the complete crystallization of Zn2GeO4.

TEM images of Zn2GeO4:Mn2+ nanoparticles aged at 200 °C for different aging times in the mixed solvent of water and diethylene glycol.Figure optionsDownload as PowerPoint slideHighlights
► Mechanism on formation of Zn2GeO4:Mn2+ nanophosphor under solvothermal condition.
► Zn2GeO4 nanorods crystallize via amorphous precursors.
► Gradual substitution of Mn2+ during prolonged aging.
► Such an inhomogeneous Mn2+ doping process results in concentration quenching.