کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1330824 | 978978 | 2011 | 9 صفحه PDF | دانلود رایگان |
From literature data presently available, the decomposition temperature and the nature of the decomposition reaction of the ternary compound α-AlFeSi (also designated as αH or τ5) are not clearly identified. Moreover, some uncertainties remain concerning its crystal structure. The crystallographic structure and thermochemical behaviour of the ternary compound α-AlFeSi were meticulously studied. The crystal structure of α-AlFeSi was examined at room temperature from X-ray single crystal intensity data. It presents hexagonal symmetry, space group P63/mmc with unit cell parameters (293 K) a=12.345(2) Å and c=26.210(3) Å (V=3459 Å3). The average chemical formula obtained from refinement is Al7.1Fe2Si. From isothermal reaction-diffusion experiments and Differential Thermal Analysis, the title compound decomposes peritectically upon heating into θ-Fe4Al13(Si), γ-Al3FeSi and a ternary Al-rich liquid. Under atmospheric pressure, the temperature of this reversible transformation has been determined to be 772±12 °C.
Partial representation of the crystal structure of the α-Al7.1Fe2Si compound.Figure optionsDownload as PowerPoint slideHighlightsThe main findings of our work are:
► a detailed X-rays crystal structure determination of the ternary compound α-AlFeSi.
► The precision of the silicon atoms positions in the crystal structure.
► A precised determination of the decomposition temperature of this compound.
Journal: Journal of Solid State Chemistry - Volume 184, Issue 5, May 2011, Pages 1120–1128