کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1331068 | 978992 | 2010 | 6 صفحه PDF | دانلود رایگان |

In this paper, we report a facile solvothermal route capable of aligning MnOOH nanocrystals on graphene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) observations indicate that the exfoliated graphene sheets are decorated randomly by MnOOH nanocrystals, forming well-dispersed graphene–MnOOH nanocomposites. Dissolution-crystallization and oriented attachment are speculated to be the vital mechanisms in the synthetic process. The attachment of additives, such as MnOOH nanoparticles, are found to be beneficial for the exfoliation of GO as well as preventing the restack of graphene sheets. Moreover, cyclic voltammetry (CV) analyses suggest that the electrochemical reversibility is improved by anchoring MnOOH on graphene. Notably, the as-fabricated nanocomposites reveal unusual catalytic performance for the thermal decomposition of ammonium perchlorate (AP) due to the concerted effects of graphene and MnOOH. This template-free method is easy to reproduce, and the process proceeds at a low temperature and can be readily extended to prepare other graphene-based nanocomposites.
Manganese oxyhydroxide nanocrystals have been successfully attached onto the graphene sheets via an oriented attachment and dissolution-crystallization process, forming a nanocomposite with unusual catalytic capabilities.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 183, Issue 11, November 2010, Pages 2552–2557