کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1331236 | 979000 | 2007 | 10 صفحه PDF | دانلود رایگان |
The structure of 14 compounds in the series Ba2LnTaO6 have been examined using synchrotron X-ray diffraction and found to undergo a sequence of phase transitions from I2/m monoclinic to I4/m tetragonal to Fm3¯m cubic symmetry with decreasing ionic radii of the lanthanides. Ba2LaTaO6 is an exception to this with variable temperature neutron diffraction being used to establish that the full series of phases adopted over the range of 15–500 K is P21/n monoclinic to I2/m monoclinic to R3¯ rhombohedral. The chemical environments of these compounds have also been investigated and the overbonding to the lanthanide cations is due to the unusually large size for the B-site in these perovskites.
The evolution of the structure across the series of double perovskites Ba2LnTaO6 is established using a combination of synchrotron X-ray and neutron diffraction. The symmetry increases from monoclinic to tetragonal and then cubic as the size of the lanthanide decreases.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 180, Issue 11, November 2007, Pages 2991–3000