کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1331860 | 979020 | 2006 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and crystal structures of La3MgBi5 and LaLiBi2 Synthesis and crystal structures of La3MgBi5 and LaLiBi2](/preview/png/1331860.png)
Two new ternary bismuthides, La3MgBi5 and LaLiBi2, have been prepared by solid-state reactions of the corresponding pure metals in welded niobium tubes at high temperature. Their structures have been established by single-crystal X-ray diffraction studies. La3MgBi5 crystallizes in the hexagonal space group P63/mcm (No.193) with cell parameters of a=b=9.7882(7)Å, c=6.5492(9)Å, V=543.41(9)Å3, and Z=2Z=2. LaLiBi2 belongs to tetragonal space group P4/nmm (No.129) with cell parameters of a=b=4.5206(4)Å, c=10.9942(19)Å, V=224.68(5)Å3, and Z=2Z=2. The structure of La3MgBi5 is of the ‘‘anti’’ Hf5Sn3Cu type, and features 1D linear Bi− anionic chains and face-sharing [MgBi6/2]7− octahedral chains. The structure of LaLiBi2 is isotypic with HfCuSi2, and is composed of 2D Bi− square sheets and 2D LiBi layers with La3+ ions as spacers. Band calculations indicate that both compounds are metallic.
Two new ternary bismuthides, namely, La3MgBi5 and LaLiBi2, have been prepared by solid-state reactions of the corresponding pure metals in welded niobium tubes at high temperature. Their structures have been established by single-crystal X-ray diffraction studies. The structure of La3MgBi5 is of the “anti” Hf5Sn3Cu type, and features 1D linear Bi− anionic chains and face-sharing [MgBi6/2]7− octahedral chains. The structure of LaLiBi2 is isotypic with HfCuSi2, and is composed of 2D Bi− square sheets and 2D LiBi layers with La3+ cations as spacers. Band calculations indicate that both compounds are metallic.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 4, April 2006, Pages 1016–1021