کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1332165 | 979032 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, structure, and physical properties of [Sm(C6NO2H5)3(H2O)2]2n.(H5O2)n(ZnCl5)n(ZnCl4)2n.(H2O)2n with unprecedented ZnCl53− species Synthesis, structure, and physical properties of [Sm(C6NO2H5)3(H2O)2]2n.(H5O2)n(ZnCl5)n(ZnCl4)2n.(H2O)2n with unprecedented ZnCl53− species](/preview/png/1332165.png)
A novel bimetallic 4f–3d metal–isonicotinic acid inorganic–organic hybrid complex [Sm(C6NO2H5)3(H2O)2]2n·(H5O2)n(ZnCl5)n(ZnCl4)2n·(H2O)2n (1) has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is characteristic of a one-dimensional polycationic chain-like structure and unprecedented ZnCl53− species. Photoluminescent investigation reveals that the title complex displays interesting emissions in a wide region. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.59 eV.
A novel bimetallic 4f–3d metal–isonicotinic acid inorganic–organic hybrid complex was synthesized. It is characteristic of a one-dimensional polycationic chain-like structure. Photoluminescent investigation reveals that the title complex displays interesting emissions in a wide region. Optical absorption spectra of 1 reveal the presence of a wide optical bandgap.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 181, Issue 8, August 2008, Pages 1853–1858