Synthesis and structure of [C6N4H20]0.5[B5O6(OH)4]: A new organically templated pentaborate with white-light-emission

A new organically templated pentaborate [C6N4H20]0.5[B5O6(OH)4] (1a) was prepared by reactions of triethylenetetramine (TETA) with excess boric acid in aqueous solution and characterized by elemental analysis, FTIR, TG-DTA, powder X-ray diffraction and photoluminescence spectroscopy. The structure of 1a was determined by a single-crystal X-ray diffraction. It crystallizes in the monoclinic system with space group P2(1)/c, a=9200(3) Å, b=14.121(5) Å, c=10.330(4) Å, β=91.512(4)°, V=1341.4(9) Å3, and Z=4. The luminescent properties of the compound were studied, and a green–blue luminescence occurs with an emission maximum at 507 nm upon excitation at 430 nm. The photoluminescence of 1a can be modified from green–blue to white by means of a simple heat-treatment process. The white-light-emission of sample 1c makes the pentaborate a good candidate for display and lighting applications in the white LED.

A green–blue luminescence occurs with an emission maximum at 507 nm upon excitation at 430 nm. The photoluminescence of 1a can be modified from green–blue to white by means of a simple heat-treatment process.Figure optionsDownload as PowerPoint slideHighlights
► A new organically templated pentaborate [C6N4H20]0.5[B5O6(OH)4] has been prepared.
► The structure of the compound is determined by single-crystal X-ray diffraction.
► Elemental analysis, FTIR, TG-DTA, powder X-ray diffraction and photoluminescence spectroscopy of the compound is investigated.
► The photoluminescence of the compound can be modified from green–blue to white by means of a simple heat-treatment process.
► The TETA molecules were diprotonated and located in the channels isolatedly as templates and counterions to compensate the negative charges of the framework.