کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1333505 | 979082 | 2006 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterisation of hexagonal molybdenum nitrides Synthesis and characterisation of hexagonal molybdenum nitrides](/preview/png/1333505.png)
Four hexagonal molybdenum nitrides—three modifications of δ-MoN and Mo5N6—were prepared by the plasma-enhanced chemical vapour deposition (PECVD) method and ammonolysis of MoCl5 and MoS2. The nitrides were structurally characterised by X-ray diffraction, high-resolution transmission electron microscopy, and selected area electron diffraction. δ1-MoN is best described by the WC-type structure with stacking faults due to nitrogen atom disorder. Ordering of nitrogen atoms results in δ2-MoN with the NiAs-type structure. Formation of trigonal molybdenum clusters in δ3-MoN is responsible for the doubling of the unit cell in a and b directions compared to δ2-MoN. Mo5N6 can be viewed as an intergrowth structure of the WC- and NiAs-type building blocks, accompanied by vacancies on Mo sites. Influence of reaction conditions on the formation of the four nitrides is discussed; their magnetic properties are presented.
Hexagonal δ2-MoN with the NiAs-type crystal structure.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 8, August 2006, Pages 2339–2348