کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1333918 979117 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crystal structure and vibrational properties of new luminescent hosts K3YF6 and K3GdF6
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Crystal structure and vibrational properties of new luminescent hosts K3YF6 and K3GdF6
چکیده انگلیسی

The luminescence hosts K3YF6 and K3GdF6 were obtained in a single-crystal form. Their crystal structure was determined from single-crystal X-ray diffraction data. Both crystals adopt monoclinic system with space group P21/n  , Z=2Z=2. Lattice parameters for K3YF6 are refined to the following values a=6.3376(13)Å, b=6.5435(13)Å, c=9.0390(18)Å, β=90.65(3)β=90.65(3) and for K3GdF6a=6.3759(13)Å, b=6.5922(13)Å, c=9.1200(18)Å, β=90.80(3)β=90.80(3). The vibrational analysis, IR and Raman spectroscopy at room temperature, was applied to these compounds in order to study the site symmetry of Y3+ and Gd3+ ions.

The coordination polyhedra of Ln, K(1) and K(2) atoms along b direction in K3LnF6.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 179, Issue 10, October 2006, Pages 3145–3150
نویسندگان
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