کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1333931 979117 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel 1D organic–inorganic hybrid based on alternating heteropolyanions [GeMo12O40]4− and isopolyanions [Mo6O22]8−
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A novel 1D organic–inorganic hybrid based on alternating heteropolyanions [GeMo12O40]4− and isopolyanions [Mo6O22]8−
چکیده انگلیسی

A novel one-dimensional (1D) coordination polymer [{Cu(2,2′-bpy)}6(Mo6O22)][GeMo12O40]·H2O (2,2′-bpy=2,2′-bipyridine), which represents the first example of 1D organic–inorganic hybrid based on a Keggin-type heteropolyanion [GeMo12O40]4− and an unprecedented isopolyanion [Mo6O22]8−, has been hydrothermally synthesized and characterized by single crystal X-ray diffraction. Crystal data: C60H50Cu6GeMo18N12O63, monoclinic, P21/c, a=13.9344(3), b=20.0329(3), c=17.2151(3) Å; β=94.0220(10)°, V=4793.70(15) Å3, T=293(2) K; Z=2.

A novel polyoxometalate [{Cu(2,2′-bpy)}6(Mo6O22)][GeMo12O40]·H2O, which represents the first example of 1D organic–inorganic hybrid based on a Keggin-type heteropolyanion [GeMo12O40]4− and an unprecedented isopolyanion [Mo6O22]8−.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 179, Issue 10, October 2006, Pages 3260–3264
نویسندگان
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