کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1333931 | 979117 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A novel 1D organic–inorganic hybrid based on alternating heteropolyanions [GeMo12O40]4− and isopolyanions [Mo6O22]8− A novel 1D organic–inorganic hybrid based on alternating heteropolyanions [GeMo12O40]4− and isopolyanions [Mo6O22]8−](/preview/png/1333931.png)
A novel one-dimensional (1D) coordination polymer [{Cu(2,2′-bpy)}6(Mo6O22)][GeMo12O40]·H2O (2,2′-bpy=2,2′-bipyridine), which represents the first example of 1D organic–inorganic hybrid based on a Keggin-type heteropolyanion [GeMo12O40]4− and an unprecedented isopolyanion [Mo6O22]8−, has been hydrothermally synthesized and characterized by single crystal X-ray diffraction. Crystal data: C60H50Cu6GeMo18N12O63, monoclinic, P21/c, a=13.9344(3), b=20.0329(3), c=17.2151(3) Å; β=94.0220(10)°, V=4793.70(15) Å3, T=293(2) K; Z=2.
A novel polyoxometalate [{Cu(2,2′-bpy)}6(Mo6O22)][GeMo12O40]·H2O, which represents the first example of 1D organic–inorganic hybrid based on a Keggin-type heteropolyanion [GeMo12O40]4− and an unprecedented isopolyanion [Mo6O22]8−.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 10, October 2006, Pages 3260–3264