کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1334061 | 979136 | 2005 | 6 صفحه PDF | دانلود رایگان |

Polycrystalline perovskite cobalt oxides (Sr1–xCax)CoO3 (0⩽x⩽0.8) were synthesized under high pressure (6 GPa) and high temperature (1200–1300 °C) conditions. Powder X-ray diffraction data confirmed that they have cubic perovskite structures. The end member of the solid solution, SrCoO3, exhibited a ferromagnetic transition with Curie temperature of Tc∼266K and metallic electric conductivity. With increasing the Ca content xx, TcTc increased slightly to 286 K at x=0.2x=0.2 then decreased rapidly to 148 K for x=0.8x=0.8. The origin of the ferromagnetism is discussed in relation to the spin state of the Co4+ ions. The present system showed a relatively large (∼5.5%) negative magnetoresistance for x=0x=0 or 0.2 in the vicinity of Tc.
Temperature dependence of the dc-magnetization M of the (Sr1–xCax)CoO3 system measured at an applied field of 1 kOe by the field cooling mode.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 178, Issue 11, November 2005, Pages 3431–3436