کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1334127 979147 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Glorious uncertainty—challenges for network design
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Glorious uncertainty—challenges for network design
چکیده انگلیسی

This article discusses the challenges that face the crystal engineer in the deliberate design of new network structures. These include control over ligand and metal coordination geometry, selection of network topology from a number of possibilities which all have the same connectivity, and control of methods of increasing packing efficiency, including interpenetration (both number of nets (including only one) and topology of interpenetration). These variables can lead to polymorphism and related phenomena, the bane of crystal engineers. Templation by counterions, guest molecules and/or solvents can also lead to unpredictable results.

The crystal engineer faces many challenges when it comes to designing new network structures; a number of these are discussed.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 178, Issue 8, August 2005, Pages 2475–2479
نویسندگان
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