Adapting wood hydrolysate barriers to high humidity conditions

The incorporation of layered silicates in bio-based barrier films resulted in lower water vapor permeability, and significantly lowered oxygen permeability at a relative humidity (RH) as high as 80%, with reduced moisture sensitivity of the wood hydrolysate (WH) based films. The applicability of WH based films was accordingly extended over a wider relative humidity condition range. Crude aqueous process liquor, the WH, was extracted from hardwood and utilized as a feed-stock for films without any upgrading pretreatment, yet producing superior oxygen barrier performance compared to partially upgraded WH and highly purified hemicelluloses. Films composed of crude WH and either one of two types of naturally occurring layered silicates, montmorillonite (MMT) or talc, as mineral additives, were evaluated with respect to oxygen and water vapor permeability, morphological, tensile and dynamic thermo-mechanical properties. Films with an oxygen permeability as low as 1.5 (cm3 μm)/(m2 day kPa) at 80% RH was achieved.

► Bio-based films were created to maintain very low oxygen permeability at high humidity conditions.
► Crude aqueous process liquor, extracted from hardwood, was used as a feed-stock for films.
► Montmorillonite particles dispersed in the films improved water and oxygen barrier performance.
► Talc particles mixed into the WH films improved the thermo-mechanical performance.