کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1383077 1500611 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold
چکیده انگلیسی


• High strength silica aerogel using cellulose nanofibrils (CNF) as scaffold was successfully prepared.
• The compressive strength of the CNF-silica composite aerogel greatly exceeded silica aerogel and the conventional insulation materials.
• The pH value of the condensation process has great influence on the properties of the CNF-silica composite aerogels.
• The CNF-silica composite aerogels are well-suited for insulation field with enhanced strength and super-hydrophobicity.

Monolithic cellulose nanofibrils (CNF)-silica composite aerogels were successfully prepared by immersing CNF aerogels into a silica solution in a two-step sol-gel process (initial hydrolysis of tetraethyl orthosilicate (TEOS) followed by condensation of silica particles). Aerogels were characterized by SEM, BET surface area test, bulk density and silica content analysis, FTIR spectroscopy, and compression test. The form of SiO2 existing in the composite aerogel was the spherical individual particles coated on CNF fibrils. The pH value of condensation solution was found to have great influence on the properties of the composite aerogels. By varying the pH value of condensation atmosphere from 8 to 12, the bulk densities of composite aerogels were able to be linearly increased from 0.059 g cm−3 to 0.29 g cm−3,and the silica content in the matrix sharply jumped from 3 wt% to 79 wt%. The porosities of the aerogels remained very high, between 85 and 96%, and the surface area of the composite aerogel reached up to 700.1 m2 g−1. The compression properties of the composite aerogel improved greatly compared with those of the silica aerogel, about 8–30 times higher. Moreover, the compressive strength of the composite aerogel prepared in this work greatly exceeded the conventional insulation materials found in the recent commercial market, and without substantial increases in thermal conductivity. Hence, the findings of this research offer a promising application for composite aerogels and give a theoretical basis for developing new advanced materials.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 147, 20 August 2016, Pages 89–96
نویسندگان
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