کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1388935 982831 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Efficient synthesis of a fluorescent tripod detection system for pesticides by microwave-assisted click chemistry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Efficient synthesis of a fluorescent tripod detection system for pesticides by microwave-assisted click chemistry
چکیده انگلیسی

A new tripod molecule containing an aromatic core bearing three peracetylated cyclodextrins was synthesized via a microwave-assisted Huisgen 1,3-dipolar cycloaddition and was studied by fluorescence spectroscopy. The photoluminescent properties of complexation phenomena with different pesticides were evaluated in acetonitrile. Fluorescence titrations have been performed to calculate binding constants, sensitivity factors, and limit of detection of the resulting complexes. 2D NMR experiments confirmed the inclusion of pesticide in the hydrophobic cavity of the macrocycle and validated the supramolecular association responsible for the quenching of the fluorescence.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 344, Issue 2, 26 January 2009, Pages 161–166
نویسندگان
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