کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1395893 | 984142 | 2013 | 11 صفحه PDF | دانلود رایگان |
Linear aliphatic polyesters having pendant hydroxyl groups were successfully synthesised by polycondensation using scandium triflate as catalyst. A first set of samples was prepared starting with hexane-, octane-, decane-, and dodecanediol and l-malic acid as hydroxyl functional dicarboxylic acid, on the one hand, and succinic acid as non-functional analogue, on the other. A second set of samples was prepared starting with different hydroxytelechelic oligo(ε-caprolactone)s, synthesised in a ring opening polymerisation (ROP) initiated by hexanediol using the same catalyst, and reacted with l-malic acid or succinic acid, respectively. The successful reaction was confirmed by nuclear magnetic resonance (NMR) spectroscopy, size exclusion chromatography (SEC), and matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry (MALDI-TOF-MS). The thermal properties of both types of polyesters – with and without pendant hydroxyl groups – were analysed by differential scanning calorimetry (DSC). While all polyesters based on succinic acid are highly crystalline, for the polyesters based on l-malic acid the crystallinity depends on the concentration of pendant hydroxyl groups and on the microstructure. Hence, the influence of the hydroxyl group enables to tailor the crystallinity.
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► Polyesters based on diols and succinic or l-malic acids were prepared.
► Polycondensation of malic acid and diols leads to linear OH-functional polyester.
► Polycondensation reactions were performed using scandium triflate as catalyst.
► The presence of OH groups decreases the crystallinity of these polyesters.
► Structure property relationships were determined.
Journal: European Polymer Journal - Volume 49, Issue 1, January 2013, Pages 217–227