کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1400370 | 1501362 | 2015 | 13 صفحه PDF | دانلود رایگان |
• The first network was synthesized via a polycondensation of PVA.
• SA molar mass influenced swelling and mechanical property of PVA semi-IPN hydrogel.
• Hydrogels achieved fracture strain of 2400% and compression stress of 35.2 MPa.
• Hydrogels could recover to initial shapes after the deformation force was removed.
Double network (DN) hydrogels have drawn much attention due to their high mechanical strength and toughness with high-water content. In this investigation, we successfully prepared extremely stretchable, transparent and tough DN hydrogels by using neutral synthetic polymer–poly(vinyl alcohol) (PVA) as the first network, polyacrylamide (PAM) as the second network and sodium alginate (SA) as a molecular stent. It was found that the content of SA significantly influenced the swelling property of PVA semi-interpenetrating polymer network (semi-IPN) hydrogel in acrylamide aqueous media and corresponding mechanical properties of DN hydrogels. The hydrogels with nearly 90 wt% water had achieved fracture strain of about 2400% and a maximum compression stress of 35.2 MPa. Moreover, we also observed the hydrogels could quickly recover to their initial shapes after the deformation force was removed. By introducing a molecular stent, we anticipated that a large number of neutral synthetic polymers would be utilized to form the first network in DN hydrogels, significantly expanding the scope of the DN hydrogel concept.
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Journal: European Polymer Journal - Volume 73, December 2015, Pages 149–161