کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1401088 984676 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel ABC2-type liquid-crystalline block copolymers with azobenzene moieties prepared by atom transfer radical polymerization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Novel ABC2-type liquid-crystalline block copolymers with azobenzene moieties prepared by atom transfer radical polymerization
چکیده انگلیسی
A series of novel ABC2-type liquid-crystalline block copolymers with azobenzene moieties in the side chains were prepared by combination of atom transfer radical polymerization (ATRP) and the chemical modification reaction. First, the bromine-terminated diblock copolymer poly(ethylene oxide) monomethyl ether-block-polystyrene (MPEO-PS-Br) was prepared by ATRP of styrene initiated with macroinitiator MPEO-Br, which was obtained from the esterification of MPEO and 2-bromoisobutyryl bromide. Then, the bromo end groups of the resulting MPEO-PS-Br were derivatized into twice as many bromoisobutyrates by the chain end modification reaction to obtain ω,ω′-bis(bromo)-PS-MPEO (MPEO-PS-Br2). The azobenzene-containing blocks of poly[6-(4-methoxy-azobenzene-4′-oxy) hexyl methacrylate] (PMMAZO) with different molecular weights were introduced into the derivative diblock copolymer by a second ATRP to synthesize the novel ABC2-type liquid-crystalline block copolymers poly(ethylene oxide) monomethyl ether-block-polystyrene-block-{poly[6-(4-methoxy-azobenzene-4′-oxy) hexyl methacrylate]}2 [MPEO-PS-(PMMAZO)2].
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 44, Issue 1, January 2008, Pages 42-49
نویسندگان
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