کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1404569 | 1501915 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
FTIR spectra of the hydrogen-bonded complex H2CS⋯HCl in solid Ar, N2, and Xe
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
Methanesulfenyl chloride and its deuterated isotopomer were photodecomposed in several low-temperature matrices and the vibrational spectra of generated thioformaldehyde⋯hydrogen chloride complexes were recorded. In solid Ar, previously unreported several modes, especially the intermolecular librational modes, were observed. The H–Cl stretching mode of the complex revealed a characteristic large red shift from the monomer frequency in Ar and N2 matrices. In addition to this large red shifted band, a relatively small shifted H–Cl stretching band was observed in a Xe matrix. The latter was considered to be due to the complex in a less-perturbed matrix site.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 797, Issues 1–3, 18 September 2006, Pages 121–130
Journal: Journal of Molecular Structure - Volume 797, Issues 1–3, 18 September 2006, Pages 121–130
نویسندگان
Eiichi Suzuki, Masahiro Yamazaki, Kenji Shimizu,