کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1404825 1501722 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of different zinc(II) oxide nano-structures from two new zinc(II)–Quinoxaline coordination polymers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of different zinc(II) oxide nano-structures from two new zinc(II)–Quinoxaline coordination polymers
چکیده انگلیسی


• Two new one-dimensional zinc(II) coordination polymers have been synthesized by slow evaporation method.
• Nano crystalline ZnO have successfully been synthesized via techniques of thermolyses.
• The final product was characterized using XRD and SEM methods.
• The same precursors to prepare ZnO nanostructure with different techniques gave us various morphologies.

Two new zinc(II) coordination polymers, [Zn(Quinoxaline)(NO3)2(H2O)2]n⋅Quinoxaline·H2O (1) and [Zn(Quinoxaline)2(Br)2]n (2), Quinoxaline = Benzopyrazine, have been synthesized and characterized by IR spectroscopy. Compounds 1 and 2 were structurally characterized by single crystal X-ray diffraction and are one-dimensional coordination polymers with coordination environment of octahedral and tetrahedral respectively. Nanostructures of zinc(II) oxide were obtained by thermolyses of compound 1 in oleic acid, calcination of compound 1 at 500 °C under air atmosphere and sol–gel processes. Also, nanopowders of zinc(II) oxide were obtained by calcination of compound 2 at 450 and 550 °C. The nanomaterials were characterized by scanning electron microscopy and X-ray powder diffraction (XRD). The thermal stability of compounds 1 and 2 both their bulk were studied by thermo-gravimetric (TGA) and differential thermal analyses (DTA). This study demonstrates the coordination polymers may be suitable precursors for the preparation of nanoscale materials.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1095, 5 September 2015, Pages 8–14
نویسندگان
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