کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1404898 | 1501726 | 2015 | 5 صفحه PDF | دانلود رایگان |
• Dimethylsulphoxide solvate of N,N′-dinaphthylthiourea posses syn-anti conformation.
• Deprotonation N,N′-dinaphthylthiourea by fluoride ions enables their visual detection.
• Copper(II) ions can be specifically detected by N,N′-dinaphthylthiourea.
• Fluoride ions enhance fluorescence of N,N′-dinaphthylthiourea whereas copper(II) ions quenches.
A dimethylsulphoxide solvate of N,N′-dinaphthylthiourea was structurally characterised and shown to have syn-anti conformation. Deprotonation of N,N′-dinaphthylthiourea by tetrabutylammonium fluoride causes specific colour change, which was studied by UV–visible, fluorescence and 1H-NMR spectroscopy. It was also observed that among various metal chlorides, copper(II) chloride specifically causes colour change on interactions with N,N′-dinaphthylthiourea which provided a means for detection of copper(II) ions, on the other hand other metal(II) chlorides were silent towards such changes. Control experiments established formation of copper thiourea complex in 1:2 metal to ligand ratio. It was also found that addition of tetrabutylammonium fluoride caused increase in fluorescence emission which was not caused by other tetrabutylammonium salts; similarly among various metal chlorides, copper(II) chloride specifically quenched fluorescence emission of N,N′-dinaphthylthiourea.
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Journal: Journal of Molecular Structure - Volume 1091, 5 July 2015, Pages 147–151