Syntheses, structures and magnetic properties of two one-dimensional coordination polymers of cobalt(II) and nickel(II) dicyanamide containing a tridentate N-donor Schiff base

Two neutral one-dimensional coordination polymers of the type [M(L)(μ1,5-dca)(dca)]n [M = Co (1), Ni (2); L = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine; dca = dicyanamide] are isolated through single-pot reactions of a 1:1:2 M ratio of M(OAc)2·4H2O, L and Na(dca) in MeOH solution at room temperature and characterized on the basis of microanalyses, spectroscopic, thermal and other physicochemical results. X-ray structural study reveals that each metal(II) center in both compounds adopts a distorted octahedral geometry with an MN6 chromophore coordinated by three N atoms of the tridentate Schiff base (L) and three nitrile N atoms of one terminal and two single μ1,5 bridged dca units in a meridional alignment; each μ1,5 bridged dca unit connects other neighboring metal centers in a non-ending fashion affording a 1D chain. Variable-temperature magnetic susceptibility measurements of 1 and 2 show weak antiferromagnetic interactions among the metal centers through μ1,5 dca bridges.

Two neutral 1D coordination polymers of the types [M(L)(μ1,5-dca)(dca)]n [M = Co (1), Ni (2); L = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine; dca = dicyanamide] have been synthesized through one-pot reactions of the building components, and characterized structurally and magneto-structurally.Figure optionsDownload as PowerPoint slideHighlights
► Neutral coordination polymers of cobalt(II) and nickel(II) are isolated using a tridentate Schiff base and dicyanamide.
► X-ray structural studies show that compounds consist of 1D covalent chains formed through single μ1,5-dicyanamide bridges.
► Thermogravimetric analyses reveal their thermal stability and decomposition pattern.
► The compounds show weak antiferromagnetic interactions mediated through dicyanamide bridge.