کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1405519 | 1501790 | 2012 | 7 صفحه PDF | دانلود رایگان |
A simple and efficient method for the conversion of alcohols and phenols to primary O-thiocarbamates and S-thiocarbamates in the absence of solvent (solvent-free condition) using silica sulfuric acid (SiO2OSO3H) as a solid acid is described. The products are easily distinguished by IR, NMR and X-ray data. X-ray data of the compounds reveal a planar trigonal orientation of the NH2 nitrogen atom with the partial C,N double-bond character and the CS or CO groups in synperiplanar position with CarylO and CalkylS moieties, respectively. Moreover, the OCSNH2 group which is perpendicular to the plane of the benzene ring in 1c and the central thiocarbamate SCONH2 group in 2b are essentially planar.
► A green and simple method for the conversion of alcohols and phenols to primary O-thiocarbamates and S-thiocarbamates.
► Using of silica sulfuric acid (SiO2OSO3H) as a solid acid in the absence of solvent (solvent-free condition).
► To report X-ray data of primary O-thiocarbamate and S-thiocarbamate for the first time.
Journal: Journal of Molecular Structure - Volume 1024, 26 September 2012, Pages 156–162