کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1406443 | 1501830 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mixed bridged dinuclear Ni(II) complex incorporating 2-pyridinealdoxime ligand: Synthesis, crystal structure and magnetic property
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Mixed bridged dinuclear Ni(II) complex incorporating 2-pyridinealdoxime ligand: Synthesis, crystal structure and magnetic property Mixed bridged dinuclear Ni(II) complex incorporating 2-pyridinealdoxime ligand: Synthesis, crystal structure and magnetic property](/preview/png/1406443.png)
چکیده انگلیسی
A complex of the composition [Ni2(Hpyco)2(epa)(EtOH)Cl3] (1) (Hpyco = pyridine-2-carbaldehyde oxime; Hepa = 3-(ethoxycarbonyl)picolinic acid) has been synthesized via solvothermal synthetic reaction, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni(II) exhibiting pseudo-octahedral geometry. An ester was formed in situ by the reaction of solvent ethanol with one carboxylic group of pyridine-2,3-dicarboxylic acid. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic NiII⋯NiII interactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 984, Issues 1–3, 15 December 2010, Pages 153–156
Journal: Journal of Molecular Structure - Volume 984, Issues 1–3, 15 December 2010, Pages 153–156
نویسندگان
Lina Zheng, Suyun Zhang, Kai Li, Wenqian Chen, Yanmei Chen, Bin Xu, Bin Hu, Yahong Li, Wu Li,