کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407322 | 1501880 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of spin-coated films of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymers by two-dimensional correlation spectroscopy
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Principal component analysis-based two-dimensional (PCA2D) correlation spectroscopy combined with the eigenvalue manipulating transformation (EMT) technique by lowering the power of a set of eigenvalues associated with the original data was applied to the temperature-dependent infrared-reflection absorption (IRRAS) spectra of spin-coated films of biodegradable P(HB-co-HHx) (HHx = 3.8, 7.2, and 10.0 mol%) copolymers. The PCA2D correlation spectra for P(HB-co-HHx) (HHx = 10.0 mol%) copolymer is completely different from those for P(HB-co-HHx) (HHx = 3.8 and 7.2 mol%) copolymers. In the synchronous PCA2D correlation spectra, the intensity changes of the bands at 1136 and 1282 cmâ1 changed greatly as HHx mol% of P(HB-co-HHx) copolymers increases. Furthermore, EMT technique accentuates the contribution of intensity of band enhanced the minor PCs, seems to preferentially emphasizes the behavior of amorphous components of during the heating process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volumes 883â884, 30 July 2008, Pages 167-172
Journal: Journal of Molecular Structure - Volumes 883â884, 30 July 2008, Pages 167-172
نویسندگان
Ho Ji, Hyonseok Hwang, Seung Bin Kim, Isao Noda, Young Mee Jung,