کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1407494 1501916 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvothermal preparation, X-ray structural characterization and properties of two novel 3D copper(I) halide/N-allyl imidazole coordination polymers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Solvothermal preparation, X-ray structural characterization and properties of two novel 3D copper(I) halide/N-allyl imidazole coordination polymers
چکیده انگلیسی

The solvothermal reactions of N-allyl imidazole with CuIX (X=Cl, Br) afford two unprecedented 3D copper(I)–olefin coordination polymer Cu2X2(N-allyl imidazole) (X=Cl for 1; Br for 2). This is the first 3D copper(I)–olefin coordination polymer synthesized in directed method, compared to most of olefin–Cu(I) coordination polymers prepared by electrochemical method. Of practical interest is that both of them contain 1D zigzag ladder chain composed of basic Cu2X2 dimer unit. Photoluminescent measurements show that 1 displays blue fluorescent emission while 2 has red fluorescent emission at room temperature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 796, Issues 1–3, 30 August 2006, Pages 210–215
نویسندگان
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