کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1407597 | 1501917 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The microwave and submillimeterwave spectrum of 13C1-methyl formate in its ground torsional state (H13COOCH3)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The rotational spectrum of 13C1 methyl formate (H13COOCH3) has been observed in the frequency range 7-610 GHz. Two hundred and ninety one transitions up to J=58 (Kmax=24) were assigned to the A-species of the ground torsional state. They could be fitted to a standard Watsonian involving 19 parameters (up to one decic centrifugal distortion constant). About 260 E-transitions were also assigned. A global analysis of all these transitions using the internal axis method gave a satisfactory fit permitting to determine the three internal rotation parameters (Iα=3.132(4) μÃ
2, V3=4912(6) J/mol and â (i,a)=52.30(5)°, which is the angle between the principal axis a and the internal rotation axis i) and allowing us to make an accurate prediction of the rotational spectrum.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 795, Issues 1â3, 21 August 2006, Pages 4-8
Journal: Journal of Molecular Structure - Volume 795, Issues 1â3, 21 August 2006, Pages 4-8
نویسندگان
F. Willaert, H. Møllendal, E. Alekseev, M. Carvajal, I. Kleiner, J. Demaison,