کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1409026 1501786 2012 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Encapsulation of vanillylamine by native and modified cyclodextrins: Spectral and computational studies
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Encapsulation of vanillylamine by native and modified cyclodextrins: Spectral and computational studies
چکیده انگلیسی

Inclusion complex formation of vanillylamine (HMBA) with α-, β-, hydroxyl propyl α- and hydroxyl propyl β-cyclodextrins were studied by absorption, steady state fluorescence, time resolved fluorescence, FT-IR, 1H NMR, molecular modeling methods. The study revealed that HMBA formed 1:1 complex with all the four CDs. Nanosecond time-resolved studies indicated that HMBA show single exponential decay in water whereas biexponential decay in CDs. Thermodynamic parameters and binding affinity of complex formation of all the CDs were determined and discussed. It was found that van der Waals interactions are mainly responsible for enthalpy-driven complex formation of HMBA with CDs.


► HMBA forms 1:1 complex with α-CD, β-CD, HPα-CD and HPβ-CD.
► CH2NH2 group present in the inner part of the CD nano-cavity.
► Biexponential decay was observed in the nanosecond time-resolved fluorescence.
► ΔG, ΔH, ΔS, and HOMO–LUMO orbital calculations confirm the better stability of the inclusion complex.
► Nanomaterial structure of the inclusion complex was different from guest and host.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1028, 28 November 2012, Pages 57–67
نویسندگان
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