کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1409695 1501829 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crystal structure, spectroscopic and redox behaviour of novel imidazolidine ligand
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Crystal structure, spectroscopic and redox behaviour of novel imidazolidine ligand
چکیده انگلیسی

In this study, the Schiff base ligand 2,2′-[2-(3,4-dichlorophenyl)imidazolidine-1,3-diyl]bis{N-[(1E)-3,4-dichlorophenyl]ethanamine} (L) was prepared and characterized by the analytical and spectroscopic methods. The 1H(13C) NMR spectra of the ligand was recorded in DMSO-d6 solvent and obtained data confirm the proposed structure. Electrochemical properties of the ligand were investigated in the DMF solvent in the range 100–250 mV s−1 scan rates. The ligand showed both reversible and irreversible processes at these scan rates. The single crystal of the ligand (L) was obtained from MeOH solution, and its crystal structure analysis was performed by X-ray diffraction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 985, Issues 2–3, 31 January 2011, Pages 167–172
نویسندگان
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