کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1409890 1501801 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new acid–base indicator containing complex: Hydrothermal synthesis, crystal structure and properties of [Cd(en)2(H2O)2](MO)2
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A new acid–base indicator containing complex: Hydrothermal synthesis, crystal structure and properties of [Cd(en)2(H2O)2](MO)2
چکیده انگلیسی

The first example of cadmium complex containing methyl orange [MO, (CH3)2NC6H4N = NC6H4SO3Na], formulated as [Cd(en)2(H2O)2](MO)21 (en = ethylenediamine) was synthesized hydrothermally and characterized by single-crystal X-ray diffraction, IR, XRD, elemental analysis and Raman spectroscopic analysis. Compound 1 display a two-dimensional supramolecular layer structure with ladder-like supramolecular chain by X-ray crystallographic analysis. MO anion immobilized by H-bonds, as acid–base indicator, shows a similar behavior in comparison with its solution counterpart in terms of response to pH.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1013, 11 April 2012, Pages 138–142
نویسندگان
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