کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1409923 1501839 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Properties of novel yellow anthraquinone dichroic dyes with naphthylthio groups for guest–host liquid crystal displays
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Properties of novel yellow anthraquinone dichroic dyes with naphthylthio groups for guest–host liquid crystal displays
چکیده انگلیسی

Yellow anthraquinone dichroic dyes, 1,5-bis(2-naphthylthio) anthraquinone 2 and 1-[4-(t-butyl)phenylthio]-5-(2-naphthylthio) anthraquinone 4 were synthesized. Dye 4 in addition to being highly soluble in fluorinated liquid crystals and having a very small temperature dependence of solubility, has a larger dichroic ratio (DR = 11.7), contrast ratio (CR = 10.7) and molar absorption coefficient (ε = 12,000) than a previous yellow anthraquinone dye 3 with two phenylthio groups owing to the effect of having a naphthylthio substituted at one of the substituents. In comparison with molecular structures of dyes 3 and 4, annulation of an arylthio group from a phenylthio group to a naphthylthio group is effective for improving these properties of dichroic dyes. Dye 4 fulfills the desired properties for guest–host liquid crystal displays to realize high performances.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 975, Issues 1–3, 30 June 2010, Pages 110–114
نویسندگان
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