کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1409946 | 1501839 | 2010 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of ligand substitution on DNA binding ability of two new square planar copper(II)–Schiff base complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of ligand substitution on DNA binding ability of two new square planar copper(II)–Schiff base complexes Effect of ligand substitution on DNA binding ability of two new square planar copper(II)–Schiff base complexes](/preview/png/1409946.png)
چکیده انگلیسی
Two terdentate NNO donor Schiff base ligands CH3C(OH)CHC(CH3)NCH2C5H4N [HL1] and C6H5C(OH)CHC(CH3)NCH2C5H4N [HL2] were used to synthesize two mononuclear square planar copper(II) complexes, [CuL1(CF3COO)] (1) and [CuL2(CF3COO)] (2). The complexes were characterized by elemental analyses, FT-IR, UV–vis spectral methods and their structures were established by single crystal X-ray diffraction study. The biochemical activity of the complexes towards DNA binding were performed using absorbance and fluorescence titration methods and their mode of binding with calf thymus DNA has been established by viscosity measurement technique.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 975, Issues 1–3, 30 June 2010, Pages 265–273
Journal: Journal of Molecular Structure - Volume 975, Issues 1–3, 30 June 2010, Pages 265–273
نویسندگان
Dipali Sadhukhan, Aurkie Ray, Saurabh Das, Corrado Rizzoli, Georgina M. Rosair, Samiran Mitra,