کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1411126 | 1501847 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural characterization and some coordinational aspects of tetrathiacalix[4]arenes functionalized by hydrazide groups
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Structural characterization and some coordinational aspects of tetrathiacalix[4]arenes functionalized by hydrazide groups Structural characterization and some coordinational aspects of tetrathiacalix[4]arenes functionalized by hydrazide groups](/preview/png/1411126.png)
چکیده انگلیسی
The structural peculiarities of tetrathiacalix[4]arenes with acetylhydrazide substitutes in cone and 1,3-alternate conformations have been determined by means of X-ray analysis, IR and NMR spectroscopy. The structural and molecular modeling data were used in the interpretation of binding properties of calix[4]arene tetrahydrazides. The quantum-chemical calculations at the DFT level using the PBE exchange-correlation functional were performed for the complexation of 1,3-alternate conformer of tetrathiacalix[4]arene with Ag+ ion. It was shown that the removal of tert-butyl groups from tert-butyltetrathiacalix[4]arene platform facilitates a bis-ligand coordination of the metal ion and leads to a remarkable increase of Ag+ extraction efficiency.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 967, Issues 1â3, 1 April 2010, Pages 72-79
Journal: Journal of Molecular Structure - Volume 967, Issues 1â3, 1 April 2010, Pages 72-79
نویسندگان
Sergey N. Podyachev, Aidar T. Gubaidullin, Victor V. Syakaev, Svetlana N. Sudakova, Aleksey N. Masliy, Alina F. Saifina, Nadezda Ð. Burmakina, Andrey M. Kuznetsov, Roald R. Shagidullin, Ludmila V. Avvakumova, Alexander I. Konovalov,