کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1411247 1501929 2006 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid state and solution behaviour of N-(2-pyridyl)- and N-(4-methyl-2-pyridyl)aminomethane-1,1-diphosphonic acids
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Solid state and solution behaviour of N-(2-pyridyl)- and N-(4-methyl-2-pyridyl)aminomethane-1,1-diphosphonic acids
چکیده انگلیسی

The crystal structures of N-(2-pyridyl)aminomethane-1,1-diphosphonic acid (1) and N-(4-methyl-2-pyridyl)aminomethane-1,1-diphosphonic acid (2) are determined and discussed with respect to their geometry and solid state organization. Compounds 1 and 2 crystallize as the opposite E and Z isomers. However, in solution both appear as a mixture of the Z and E forms. From the temperature dependence of NMR spectra, the Z/E ratio is assigned to be nearly equal in 1 and 0.69:0.31, respectively, in 2. The role of a substituent position on the pyridyl ring for the Z/E ratio in solution and for solid state conformations of N-(2-pyridyl)aminomethane-1,1-diphosphonic acids is discussed as well.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 782, Issues 2–3, 23 January 2006, Pages 81–93
نویسندگان
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